CHEMICAL RISK ASSESSMENT TEMPLATE Company: [COMPANY NAME] Assessment Area: [AREA/PROCESS] Assessment Date: [DATE] Assessed by: [NAME & POSITION] Review Date: [DATE] Assessment Reference: [REF NUMBER] CHEMICAL INFORMATION: Chemical Name: [CHEMICAL NAME] Trade Name: [TRADE/BRAND NAME] CAS Number: [CAS NUMBER] Supplier: [SUPPLIER NAME] SDS Date: [SDS DATE] Physical Form: □ Solid □ Liquid □ Gas □ Vapor □ Aerosol Quantity Used: [AMOUNT] per [TIME PERIOD] Storage Quantity: [AMOUNT] HAZARD CLASSIFICATION: GHS HAZARD CLASSES: □ Explosives □ Flammable gases □ Flammable liquids □ Flammable solids □ Oxidizing substances □ Organic peroxides □ Toxic substances □ Corrosive substances □ Irritant substances □ Sensitizing substances □ Carcinogenic substances □ Mutagenic substances □ Reproductive toxins □ Environmental hazards HEALTH HAZARDS: □ Acute toxicity (oral, dermal, inhalation) □ Skin corrosion/irritation □ Eye damage/irritation □ Respiratory sensitization □ Skin sensitization □ Germ cell mutagenicity □ Carcinogenicity □ Reproductive toxicity □ Target organ toxicity (single exposure) □ Target organ toxicity (repeated exposure) □ Aspiration hazard PHYSICAL HAZARDS: □ Explosive □ Flammable □ Oxidizing □ Corrosive to metals □ Gas under pressure □ Self-heating □ Pyrophoric □ Self-reactive □ Organic peroxide EXPOSURE ASSESSMENT: ROUTES OF EXPOSURE: □ Inhalation □ Skin contact □ Eye contact □ Ingestion □ Injection EXPOSURE SCENARIOS: Scenario 1: [NORMAL OPERATIONS] Description: [DETAILED DESCRIPTION OF NORMAL USE] Duration: [TIME PERIOD] Frequency: [HOW OFTEN] Concentration/Amount: [ESTIMATED EXPOSURE LEVEL] Workers Exposed: [NUMBER AND TYPES] Scenario 2: [MAINTENANCE/CLEANING] Description: [DETAILED DESCRIPTION] Duration: [TIME PERIOD] Frequency: [HOW OFTEN] Concentration/Amount: [ESTIMATED EXPOSURE LEVEL] Workers Exposed: [NUMBER AND TYPES] Scenario 3: [EMERGENCY/SPILL RESPONSE] Description: [DETAILED DESCRIPTION] Duration: [TIME PERIOD] Frequency: [HOW OFTEN] Concentration/Amount: [ESTIMATED EXPOSURE LEVEL] Workers Exposed: [NUMBER AND TYPES] EXPOSURE LIMITS: OSHA PEL: [VALUE] [UNITS] ACGIH TLV: [VALUE] [UNITS] NIOSH REL: [VALUE] [UNITS] Company Limit: [VALUE] [UNITS] STEL (15-min): [VALUE] [UNITS] Ceiling Limit: [VALUE] [UNITS] RISK CHARACTERIZATION: INHALATION RISK: Exposure Level: [MEASURED/ESTIMATED] Exposure Limit: [APPLICABLE LIMIT] Risk Ratio: [EXPOSURE/LIMIT] Risk Level: □ Low □ Medium □ High Comments: [ASSESSMENT NOTES] SKIN CONTACT RISK: Potential for Contact: □ Minimal □ Occasional □ Frequent Skin Absorption: □ Yes □ No □ Unknown Protective Measures: [CURRENT CONTROLS] Risk Level: □ Low □ Medium □ High Comments: [ASSESSMENT NOTES] EYE CONTACT RISK: Potential for Contact: □ Minimal □ Occasional □ Frequent Severity of Effects: □ Mild irritation □ Serious damage Protective Measures: [CURRENT CONTROLS] Risk Level: □ Low □ Medium □ High Comments: [ASSESSMENT NOTES] CONTROL MEASURES: HIERARCHY OF CONTROLS: 1. ELIMINATION: □ Substitute with safer alternative □ Eliminate process requiring chemical Current Status: [IMPLEMENTED/NOT FEASIBLE/UNDER CONSIDERATION] Comments: [DETAILS] 2. SUBSTITUTION: □ Less hazardous chemical □ Different physical form □ Lower concentration Alternative Options: [LIST ALTERNATIVES CONSIDERED] Current Status: [IMPLEMENTED/NOT FEASIBLE/UNDER CONSIDERATION] Comments: [DETAILS] 3. ENGINEERING CONTROLS: □ Local exhaust ventilation □ General ventilation □ Enclosed processes □ Automation/remote operation □ Isolation/containment Current Controls: [DESCRIBE EXISTING CONTROLS] Effectiveness: □ Adequate □ Needs improvement □ Inadequate Additional Controls Needed: [SPECIFY] 4. ADMINISTRATIVE CONTROLS: □ Work procedures/SOPs □ Training programs □ Job rotation □ Access restrictions □ Warning signs/labels □ Exposure monitoring Current Controls: [DESCRIBE EXISTING CONTROLS] Effectiveness: □ Adequate □ Needs improvement □ Inadequate Additional Controls Needed: [SPECIFY] 5. PERSONAL PROTECTIVE EQUIPMENT: □ Respiratory protection □ Chemical-resistant gloves □ Chemical-resistant clothing □ Eye/face protection □ Emergency equipment Current PPE: [DESCRIBE CURRENT PPE] Effectiveness: □ Adequate □ Needs improvement □ Inadequate Additional PPE Needed: [SPECIFY] STORAGE AND HANDLING: STORAGE REQUIREMENTS: □ Segregation from incompatibles □ Temperature control □ Ventilation requirements □ Secondary containment □ Fire protection □ Security measures Current Storage: [DESCRIBE CURRENT STORAGE] Deficiencies: [LIST ANY DEFICIENCIES] HANDLING PROCEDURES: □ Written procedures available □ Training provided □ Supervision adequate □ Equipment appropriate □ Emergency procedures Current Procedures: [DESCRIBE CURRENT PROCEDURES] Improvements Needed: [LIST IMPROVEMENTS] INCOMPATIBLE MATERIALS: [LIST CHEMICALS THAT MUST BE KEPT SEPARATE] EMERGENCY PROCEDURES: SPILL RESPONSE: Small Spills: [PROCEDURE] Large Spills: [PROCEDURE] Equipment Required: [LIST EQUIPMENT] Personnel Training: [TRAINING STATUS] EXPOSURE RESPONSE: Inhalation: [FIRST AID PROCEDURE] Skin Contact: [FIRST AID PROCEDURE] Eye Contact: [FIRST AID PROCEDURE] Ingestion: [FIRST AID PROCEDURE] FIRE/EXPLOSION RESPONSE: Extinguishing Media: [APPROPRIATE EXTINGUISHERS] Special Hazards: [COMBUSTION PRODUCTS, ETC.] Fire Fighting Procedures: [SPECIAL PROCEDURES] WASTE DISPOSAL: Disposal Method: [APPROVED DISPOSAL METHOD] Waste Classification: [HAZARDOUS/NON-HAZARDOUS] Disposal Contractor: [CONTRACTOR NAME] Documentation: [MANIFESTS, CERTIFICATES] MONITORING REQUIREMENTS: EXPOSURE MONITORING: Monitoring Required: □ Yes □ No Frequency: [SCHEDULE] Method: [SAMPLING/ANALYTICAL METHOD] Personnel Monitored: [WHO GETS MONITORED] Action Levels: [LEVELS REQUIRING ACTION] HEALTH SURVEILLANCE: Medical Surveillance Required: □ Yes □ No Type of Surveillance: [MEDICAL EXAMS, TESTS] Frequency: [SCHEDULE] Medical Provider: [PROVIDER NAME] Records Maintenance: [RECORD KEEPING REQUIREMENTS] ENVIRONMENTAL MONITORING: Air Monitoring: □ Required □ Not Required Water Monitoring: □ Required □ Not Required Soil Monitoring: □ Required □ Not Required Waste Monitoring: □ Required □ Not Required TRAINING REQUIREMENTS: GENERAL CHEMICAL SAFETY: □ Hazard communication training □ SDS interpretation □ Labeling systems □ Emergency procedures □ PPE selection and use SPECIFIC CHEMICAL TRAINING: □ Chemical-specific hazards □ Safe handling procedures □ Exposure controls □ Emergency response □ Waste disposal SPECIALIZED TRAINING: □ Respiratory protection □ Confined space entry □ Hazardous waste operations □ Emergency response □ Medical surveillance TRAINING RECORDS: Training Provider: [PROVIDER] Last Training Date: [DATE] Next Training Due: [DATE] Training Documentation: [LOCATION OF RECORDS] REGULATORY COMPLIANCE: APPLICABLE REGULATIONS: □ OSHA Hazard Communication Standard □ OSHA Respiratory Protection Standard □ OSHA PPE Standards □ EPA TSCA Requirements □ DOT Shipping Regulations □ Local Environmental Regulations REQUIRED DOCUMENTATION: □ Safety Data Sheets current and accessible □ Chemical inventory maintained □ Training records current □ Exposure monitoring records □ Medical surveillance records □ Waste disposal documentation PERMITS/REGISTRATIONS: □ Air emissions permits □ Waste disposal permits □ Storage permits □ Transportation permits RISK EVALUATION: OVERALL RISK ASSESSMENT: Inhalation Risk: □ Low □ Medium □ High Skin Contact Risk: □ Low □ Medium □ High Eye Contact Risk: □ Low □ Medium □ High Fire/Explosion Risk: □ Low □ Medium □ High Environmental Risk: □ Low □ Medium □ High OVERALL RISK LEVEL: □ Low □ Medium □ High RISK ACCEPTABILITY: □ Risk acceptable with current controls □ Risk acceptable with additional controls □ Risk unacceptable - immediate action required ACTION PLAN: IMMEDIATE ACTIONS (24 hours): 1. [ACTION ITEM] Responsible: [NAME] Due Date: [DATE] 2. [ACTION ITEM] Responsible: [NAME] Due Date: [DATE] SHORT-TERM ACTIONS (30 days): 1. [ACTION ITEM] Responsible: [NAME] Due Date: [DATE] 2. [ACTION ITEM] Responsible: [NAME] Due Date: [DATE] LONG-TERM ACTIONS (90 days): 1. [ACTION ITEM] Responsible: [NAME] Due Date: [DATE] 2. [ACTION ITEM] Responsible: [NAME] Due Date: [DATE] REVIEW AND UPDATE: REVIEW TRIGGERS: □ Annual review □ Change in process □ New exposure data □ Incident occurrence □ Regulatory changes □ SDS updates NEXT REVIEW DATE: [DATE] APPROVAL: Chemical Risk Assessment Completed by: Name: _________________ Position: _________________ Signature: _________________ Date: _________________ Reviewed by Industrial Hygienist: Name: _________________ Position: _________________ Signature: _________________ Date: _________________ Approved by Safety Manager: Name: _________________ Position: _________________ Signature: _________________ Date: _________________ Document Control: Version: 1.0 Document ID: CRA-[CHEMICAL]-001 Next Review: [DATE] Distribution: [LIST RECIPIENTS]